Biobutanol has been used as a fuel in motor racing in the recent past. A DuPont-Shell joint venture was producing it from wood waste and other biomass in the early 2010s, and because it could be freely blended with gasoline, it was adopted in the American Le Mans Series for a time.
Because it has a higher energy density than ethanol, it had some benefits in terms of vehicle packaging and fewer pit stops.
IndyCar used denatured ethanol for many years. Not sure what they will be using under the new rules package, now that Shell is the fuel sponsor (real Shell, not Motiva).
Total supplies the World Endurance Championship with a synthetic fuel derived from wine waste.