Bill Walker said:
I can think of some really fun experiments to prove or disprove this, if somebody has a whole lot of money.
I sense a "Mythbusters" episode...
BTW, smoke from an incomplete combustion (oxygen starved) can also make a nice explosive mixture. There were a few airliner incidents involving smoldering cabin fires that built up hot smoke while in flight, which "flashed over" when the cabin doors were opened admitting oxygen. (See NFPA 921 for a complete description of flash over.)
Some years back I happened upon a truck full of energetics - fireworks, initially, followed by a lot of hydrocarons [gas? fiberglass? plastic?] - merrily burning away at the side of the road. One of the more interesting phenomena was that the plume of thick black smoke would occasionally turn itself inside out and burst into flame 50 feet up... presumably unburned but vaporized and superheated hydrocarbons were sucked up into the plume, shrouded by CO2 and smoke, exposed suddenly to the air at some point, and would then mix & combust. Entertaining as all getout... but not *explosive.* No supersonic shocks formed, just some rapid deflagration.
I can see a flashover event in a jetliner... packed as they are with burnable, meltable and vaporizable plastics. And while I can see the sudden pressure rise from a flashover causing the fuselage to burst... shredding the craft barrel-bomb style just doesn't make sense to me.
I bow to my learned colleague's superior knowledge in the fields of intentional explosives. I make my living off the accidental stuff.
In better days I was the Junior Blow Stuff Up Guy at United Tech. "Accidental explosions" were really, really bad, while "intentional explosions" were *fun.* It was one of the former that caused United Tech to fold up like a road map.
FYI: timing is everything when it comes to the difference between deflagration and detonation. Example, start with a match, a cup of liquid oxygen and a charcoal briquette:
1) Light charcoal. Pour on LOX. Result: a fast bright fire that eats through your BBQ and scares the people standing around the BBQ.
2) Put briquette into cup, allowing the briquette to soak up the LOX. Throw match at briquette. Result: about half a stick of dynamite, sending chunks of the BBQ into the people standing around, killing many.
Same stuff in the same ratios. Very different results.