Another reason for a precessing series of Molniya orbiting assets is to fill in the gaps.
With asteroid deflection you want a slight deviation to build...an inch to the side for every 400 km or something.
With a Molniya orbit, a slight thrust at or right after apogee can allow a strike from above to open that ground track path a bit more on its own.
Insert comet like orbit for Molniya--you are thinking North-South...but a comet like orbit need not be a polar orbit...
Just no. Again, there are no "gaps" to fill. The whole northern hemisphere is unreachable from a Molniya orbit. Look at the pic I posted. North America, Europe and Asia are unreachable.
A Molniya orbit is very specific. It is at an inclination of 63.4 degrees with an argument of perigee of 270 degrees, and an orbital period of 12 hours. Can't substitute for any parameter or it is not a Molniya.
And if you want to talk just highly elliptical orbits, they are still unusable for this
For a quick response from orbit, the following is required:
1. Orbit with inclinations that cover the areas to be targeted. That would be 70 degrees or higher.
2. Circular so that entry can be initiated from any point in the orbit
3. A repeating orbit that follows the same ground path (this is determined by altitude and inclination)
4. Multiple orbits in use for quicker response time
#2, 3 & 4 along with the number of weapons in orbit will determine response time.
The RVs need to be maneuverable and the bus needs delta V for off track targeting.