if my calculations are right...
Imagine some big S-IVB. It weighed 115 mt, exactly half the Stratolaunch payload of 250 mt.
https://en.wikipedia.org/wiki/S-IVB
The S-IVB weighed 115 mt with full tanks and 11 mt with empty tanks.
Now if we double the weights, then 230 mt full and 22 mt empty.
PGA can certainly do much better than old J-2, specific impulse 455 seconds.
so the stage has a delta-v = 9.81*455*ln(230/22) = 10476 m/s.
Good, this is far more than Earth orbit, let's say 9100 m/s. So we have a payload !
Then...
A study by Klijn et al. concluded that at an altitude of 15,250 m, a rocket launch with the carrier vehicle having a zero launch velocity at an angle of attack of 0° to the horizontal experienced a Δv benefit of approximately 600m/s. The zero launch velocity situations can be used to represent the launch from a balloon as it has no horizontal velocity.
While a launch at a velocity of 340m/s at the same altitude and angle of attack resulted in a Δv benefit of approximately 900m/s.
Furthermore, by increasing the angle of attack of the carrier vehicle to 30° and launching at 340m/s, they obtained a Δv gain of approximately 1,100m/s.
So we can substract 1100 m/s out of 9100 m/s - our delta-v objective is now 8000 m/s.
So what payload can that big stage orbit if air-dropped from the Roc ?
+20 mt
delta-v = 9.81*455*ln(250/42) = 7962 m/s
Barely enough.
Hence if Roc had, from the beginning, a huge LOX/LH2 stage (think oversized SLS upper stage), pushing hard with PGA, payload could have been slightly less than 20 mt, probably 18 mt - 45 000 pounds for you imperial maniacs.