The Horton Brothers flew an Hols Der Teufel based primary glider in May 36 made almost entirely from a paper and resin composite known as Astralon. They followed this up with the Horton 5A flying wing which flew (briefly, crashed just after takeoff on its 1st flight ) under its power in June 37. The Hols Der Teufel and Horton 5A used a traditional spar, rib and skin structural architecture with a large TE area’s, fabric covered. The ribs where hot pressed to form a lattice shape. The single Horton 4b featured 3 individual moulded Dynal/Tronal (K.Stopf) leading edge panels per wing bonded on a Aluminium spar. However it’s wing fluttered badly ultimately leading to its loss.
GRP - I understand the first flying non structural GRP composite parts appeared in WW2 in the US;- minor bits of Corsair and B29. The first primary flying structure in GRP (glass fibre in polyester?) was the Vought Prirate tail plane, specifically “Fabrilite” used in the fin and rudder. (First flight Oct 46).
As said above, a non GRP based composite fuselage structure (flax-phenolic known as Aeroplastic) was trialed for a Spitfire fuselage, non flying, one-off. Less well known is this material actually made it into production on the Miles Magister horizontal tailplanes with 300 delivered starting in late 43.
After this, the Brits were going in the right direction with the Miles M76 Crabpot glider, but the Miles bankruptcy (withdrawal from aeroplanes) stopped its development. I’ve seen a reference that it’s vacuum moulded woven asbestos cloth/phenolic composite, paper honeycomb sandwich wing was statically tested at RAE Farnborough in early 47. Smaller components such as the root rib were manufactured from GRP. This suggests it was manufactured in 46 and its two 30ft span wings were the largest single pieces of composite made at that time. Following Miles’s closure in mid 47, the Crabpot was finished by a former employee (renamed the Kendal K1) and flew albeit without any composite ie it had a new all wood wing built by EoN. In the late 40’s Shorts designed and flew the Nimbus glider which used asbestos fibres in a polyester resin in some of its primary structure, but I’ve been unable to find out what specifically and most reference’s describe it as a wooden airframe.
But all that said the Germans got the title of the first all GRP aeroplane with the Phoenix.